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Physical properties of PTFE and filler

PTFE Properties

 

1. Insulation

 

PTFE is not affected by the environment and frequency.  The volume resistance can reach 1018 ohm/cm, the dielectric loss is small, and the breakdown voltage is high.

 

2. High and Low Temperature Resistance

 

The influence on the temperature change is not much to PTFE.  The working temperature is significant, ranging from -190 to +260 °C.

 

3. Self-lubricating

 

PTFE has the lowest friction coefficient in plastic and is an ideal oil-free lubricating material.

 

4. Non-sticking Surface

 

None of solid materials known can adhere to PTFE's surface.  It is a solid material with the smallest surface energy.

 

5. Resistance to Atmospheric Aging, Radiation And Low Permeability

 

Long-term exposure to the atmosphere, surface and performance remain unchanged.

 

6. Non-combustibility

 

The oxygen limit index is below 90.

 

7. Chemical and Weather Resistance

 

In addition to molten alkali metal, PTFE is hardly corroded by any chemical agents.  For example, in concentrated sulfuric acid, nitric acid, hydrochloric acid, or even boiling in aqua regia, there is no change in weight and properties, and it is almost insoluble in all solvents, and is slightly soluble in per-alkanes (about 0.1 g/100 g) only above +300 °C.

 

8. PTFE does not absorb moisture, and is non-combustible and extremely stable to oxygen and ultraviolet rays, and has excellent weather resistance.

 

PTFE Properties

 

Physical Characteristics

Unit

Value

Density

g/cm3

2.14-2.22

Water Absorption Rate(24h)

%

<0.05

Ultimate Oxygen

%

>95

Tensile Strength

Mpa

21.1-28.0

Heat of Combustion

MG/kg

4.9-5.0

Elongation(25℃)

%

200-400

Bending Strength

Mpa

11-14

Compressive Strength

Mpa

7

Impact Strength

KJ/㎡

100

Hardness

Shore Hardness

D50-D65

Dynamic & Static Friction Coefficient

/

0.04

Crystal Melting Point

327

Heat Distortion Temperature

120

Glass Transition Temperature

-120

Operating Temperature

-180 ~ +250

Decomposition Temperature

>415

Thermal Conductivity Coefficient

W/km

0.24

Linear Expansion Coefficient

1/℃

1.09*104~2.165*104

DC Breakdown Voltage

KV/mm

>60

Dielectric Constant 106 Weeks

/

1.8-2.2

Dielectric Loss Tangent 106 Weeks

/

<2.5*104

Resistivity

Ω .m

>106

Arc Resistance

sec

<160

 

Enhanced PTFE performance

 

Polytetrafluoroethylene (PTFE) has excellent heat resistance, chemical resistance, non-adhesiveness and weather resistance, but it has a large linear expansion coefficient, poor dimensional stability, low hardness, and poor wear resistance.  Under the load, PTFE shows a large "cold flow", which limits its application.  In order to overcome the shortcomings to meet different application requirements, PTFE can be modified by adding an appropriate amount of filler to achieve excellent wear resistance, high temperature resistance, high strength, high stiffness and dimensional stability while maintaining low friction characteristics.  Fillers include glass fiber, para-polyphenylene. , molybdenum disulfide, polyphenylester, graphite, carbon powder, carbon fiber, bronze powder, silicon powder, etc..

 

Reinforcement of PTFE by Filling Modified Materials

 

Filler

Improved Performance

Glass Fiber

Improve compressive strength, stiffness, wear resistance, reduce cold flow, and resist organic solvents.

Carbon

Improve tensile strength, hardness, wear resistance, high temperature resistance, and thermal conductivity.

Carbon Fiber

Improve compression creep resistance, cold flow resistance, high temperature resistance, and thermal conductivity.

Graphite

Improve lubricity and thermal conductivity, and reduce friction coefficient.

Bronze

Improve tensile strength, hardness, wear resistance, thermal conductivity, and reduce cold flow.

Polyphenylester

Improve creep resistance, dimensional stability, and high temperature resistance.

Stainless Steel

Increase heat transfer coefficient, reduce cold flow, and resist chemical corrosion.

Glass Emblem

Improve compression and flexibility under low stress.

Diatomaceous Earth 

Improve compression creep resistance, improves porosity and flexibility.


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